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十一烯醇 /10-Undecen-1-ol {[allProObj[0].p_purity_real_show]}

货号:A849391

10-Undecen-1-ol, converted from ricinoleic acid, can be used as a comonomer for the introduction of functional groups .

10-Undecen-1-ol 化学结构 CAS号:112-43-6
10-Undecen-1-ol 化学结构
CAS号:112-43-6
10-Undecen-1-ol 3D分子结构
CAS号:112-43-6
10-Undecen-1-ol 化学结构 CAS号:112-43-6
10-Undecen-1-ol 3D分子结构 CAS号:112-43-6
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10-Undecen-1-ol 纯度/质量文件 产品仅供科研

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10-Undecen-1-ol 生物活性

描述 10-Undecen-1-ol is a chemical substances. By pre-treating with equimolar amounts of alkylaluminums, functional alpha-olefin 10-undecen-1-ol can be efficiently incorporated into polyethylene chains. 10-Undecen-1-ol incorporation can easily reach 15.8 mol% under the mild conditions. When compared with VCl3(THF)3 or rac-Et[Ind]2ZrCl2, these vanadium(III) complexes exhibited higher activities towards the copolymerization, and can incorporate more 10-undecen-1-ol into polymer chains under the similar conditions[3]. Direct UV photochemical functionalization of H-terminated Si(111) with bifunctional 10-undecen-1-ol was achieved with selective attachment via its vinyl end, resulting in the formation of a compact monolayer with free terminal alcohol groups. This is due to the faster radical propagation mechanism in hydrosilylation with alkene compared to the nucleophilic attack mechanism of alcohol, which is impeded by intermolecular hydrogen bonding present at room temperature[4]. The polyester channels modified with 10-undecen-1-ol exhibited a dramatically high-separation efficiency compared with the conventional fused-silica capillary tubes[5].

10-Undecen-1-ol 参考文献

[1]Quinzler D, et al. Renewable resource-based poly(dodecyloate) by carbonylation polymerization. Chem Commun (Camb). 2009;(36):5400-5402.

[2]Jonas U. A, et al. Functional Beads of Polyvinylpyrrolidone: Promising Support Materials for Solid‐Phase Synthesis.

[3]Xu BC, Hu T, Wu JQ, Hu NH, Li YS. Novel vanadium(III) complexes with bidentate N,N-chelating iminopyrrolide ligands: synthesis, characterization and catalytic behaviour of ethylene polymerization and copolymerization with 10-undecen-1-ol. Dalton Trans. 2009;(41):8854‐8863

[4]Zhong YL, Bernasek SL. Direct photochemical functionalization of Si(111) with undecenol. Langmuir. 2011;27(5):1796‐1802

[5]Xu W, Uchiyama K, Shimosaka T, Hobo T. Fabrication of polyester microchannels and their applications to capillary electrophoresis. J Chromatogr A. 2001;907(1-2):279‐289

10-Undecen-1-ol 实验方案

计算器
存储液制备 1mg 5mg 10mg

1 mM

5 mM

10 mM

5.87mL

1.17mL

0.59mL

29.36mL

5.87mL

2.94mL

58.72mL

11.74mL

5.87mL

10-Undecen-1-ol 技术信息

CAS号112-43-6
分子式C11H22O
分子量 170.292
别名
运输蓝冰
存储条件

液体 -20°C:3-6个月-80°C:12个月

溶解度

DMSO: 105 mg/mL(616.59 mM),配合低频超声助溶,注意:DMSO长时间开封后,会吸水并导致溶解能力下降,请避免使用长期开封的DMSO

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