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10-Undecen-1-ol

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Chemical Structure| 112-43-6 同义名 : -
CAS号 : 112-43-6
货号 : A849391
分子式 : C11H22O
纯度 : 98%
分子量 : 170.292
MDL号 : MFCD00004750
存储条件：

粉末 Inert atmosphere,Room Temperature

液体 -20°C:3-6个月-80°C:12个月
溶解度 :

DMSO: 105 mg/mL(616.59 mM)，配合低频超声助溶，注意：DMSO长时间开封后，会吸水并导致溶解能力下降，请避免使用长期开封的DMSO
动物实验配方：
生物活性
描述 10-Undecen-1-ol is a chemical substances. By pre-treating with equimolar amounts of alkylaluminums, functional alpha-olefin 10-undecen-1-ol can be efficiently incorporated into polyethylene chains. 10-Undecen-1-ol incorporation can easily reach 15.8 mol% under the mild conditions. When compared with VCl3(THF)3 or rac-Et[Ind]2ZrCl2, these vanadium(III) complexes exhibited higher activities towards the copolymerization, and can incorporate more 10-undecen-1-ol into polymer chains under the similar conditions[3]. Direct UV photochemical functionalization of H-terminated Si(111) with bifunctional 10-undecen-1-ol was achieved with selective attachment via its vinyl end, resulting in the formation of a compact monolayer with free terminal alcohol groups. This is due to the faster radical propagation mechanism in hydrosilylation with alkene compared to the nucleophilic attack mechanism of alcohol, which is impeded by intermolecular hydrogen bonding present at room temperature[4]. The polyester channels modified with 10-undecen-1-ol exhibited a dramatically high-separation efficiency compared with the conventional fused-silica capillary tubes[5].
实验方案
1mg 5mg 10mg

1 mM

5 mM

10 mM

5.87mL

1.17mL

0.59mL

29.36mL

5.87mL

2.94mL

58.72mL

11.74mL

5.87mL
参考文献

[1]Quinzler D, et al. Renewable resource-based poly(dodecyloate) by carbonylation polymerization. Chem Commun (Camb). 2009;(36):5400-5402.

[2]Jonas U. A, et al. Functional Beads of Polyvinylpyrrolidone: Promising Support Materials for Solid‐Phase Synthesis.

[3]Xu BC, Hu T, Wu JQ, Hu NH, Li YS. Novel vanadium(III) complexes with bidentate N,N-chelating iminopyrrolide ligands: synthesis, characterization and catalytic behaviour of ethylene polymerization and copolymerization with 10-undecen-1-ol. Dalton Trans. 2009;(41):8854‐8863

[4]Zhong YL, Bernasek SL. Direct photochemical functionalization of Si(111) with undecenol. Langmuir. 2011;27(5):1796‐1802

[5]Xu W, Uchiyama K, Shimosaka T, Hobo T. Fabrication of polyester microchannels and their applications to capillary electrophoresis. J Chromatogr A. 2001;907(1-2):279‐289